Nuclear ChemistryChapter 25, chapter 4, section 4.4

 

Nuclear chemistry is the study of the ________________ of atoms and the ____________________ they undergo.

 

What makes an ordinary chemical reaction different than a nuclear reaction?

 

Chemical Reactions

Nuclear Reactions

Bonds are ____________ and reformed.

Nuclei release particles and rays of __________

 

Atoms ____________________ but are unchanged in structure.

Atoms are often __________________into atoms of another element.

 

Involve only ____________________ electrons

Can involve protons, neutrons, and even ____________________

 

Small _________________ changes occur .

________________ energy changes occur

 

Rate of the reaction is influenced by ____________________, pressure, concentration, and ________________________.

Rate of the reaction is not effected by the factors

 

The Nucleus

 

Ø      Contains __________________ and neutrons.  They are collectively called _____________________.

Ø      There are 2 forces within the nucleus.  _______________________________ where protons repel other protons. (___________________________________).  The other is called a ______________________ which keeps the protons and neutrons together.

Ø      A _____________________ nucleus holds together well.                

 

Band of Stability          

What causes a nucleus to decay?

                                   

Ø      Some atoms decay (__________________________) because they have unstable nuclei.

 

Ø      Elements falling ____________ or below the band of stability are unstable and are called __________________________.  They will decay releasing a particle and/or_________________.

 

Transmutation

 

Ø      Type of nuclear reaction that will change the number of ___________________ and thus will create a different ________________________. 

 

 

Types of Radioactive Decay

                                               

Type                      Symbol        What Happens?           Example                      Penetrating Power

 

Alpha

 

(Happens to elements above#83)

alpha particle   or  Helium nuclei

Atomic number decreases by ____ and mass number decreases by ____2

 

(1) LOW:  Can be blocked by the skin

 

***Beta

(Happens to elements with a high n/p ratio)

electronor Beta particle

Atomic number increases by _____ but the mass number stays the same

 

(100) MEDIUM: can penetrate the skin; need to be protected by clothing

Gamma

gamma radiation

No change in atomic nor mass number; occurs with other types of ____________

 

(100000)  HIGH: need to be protected by lead

 

*** A neutron becomes a ________________ and a high speed electron that is discharged from the nucleus.

 

Writing Balanced Nuclear Equations

 

The ______________________ and mass number must be _____________________ on both sides of the equation.

 

 
 

 


Alpha Decay of thorium-230         

 

 

 

 
 


Beta Decay of thorium -234            

 

 

 

You Try!

  1. Beta decay of zircomium-97

 

 

  1. alpha decay of americium-241

 

 

  1. alpha decay of uranium-238

 

 

 

  1. Complete this: 239                    239                 

                                           Np   à              Pu     + ___________

                                     93                      94

 

Bombarding the Nucleus

 

Ø      All _________________________ elements( ____________________) are made through this process in nuclear reactors and _________________________________.

 

Example:

 
 


    

 

 

 

 

 

 

Half Life

 

Ø      Radioactive isotopes decay at a characteristic rate measured in ____________________.

Ø      A half life is the time required for _____________ of the radioactive nuclei to decay. They range from __________________ to millions of _____________________.

 

T= elapsed time

T1/2 = half life

 

HOW TO’s

1.  To calculate the number of half lives, divide the half life(T1/2) into the time (T).

 

T/T1/2 = # of half lives

 

2.  Equation to calculate remaining amount left over after a certain number of half lives have passed.

 

Amt remaining = (initial amt) (.5)n (# of half lives)

__________________________________________________________________________

Refer to Half Life Lab

__________________________________________________________________________

 

Examples:  Suppose you have 20 grams of sodium-24.  Its half-life is 15 hours.  How much is left over after 60 hours.

 

 

 

 

Uranium-238 has a half life of 4.46 x 109 years.  How long will it take for 7/8th of the sample to decay?

 

 

 

 

You Try!

The half life of radium-222 is 38 s.  How many grams of a 12.0 g sample are left after 114 s?

 

 

 

 

 

 

Nuclear Fusion

v     Small atoms  are _______________________ to formfusion reaction - Nuclear Fusion of Two Hydrogen Isotopes
 

a large atom.

v     Occurs in the _____________and _____________

v     Generates huge amounts of ____________________

 

 

 

 

 

 

 

 

Nuclear Fission

v     Large atoms _______________ into smaller atoms

v     Generates huge amounts of ___________________.fission reaction - The Fission Reaction of Uranium-235

v     Used in ___________________power plants.

v     Could result in a _______________________ of fission like the _____________________

 

 

 

 

Tutorials:

 

Nuclear Reactions:http://ithacasciencezone.com/chemzone/lessons/11nuclear/dcayquiz.htm

Half Life & Nuclear Reactions: http://www.glencoe.com/qe/science.php?qi=2696\